Even though LED lights are among the most energy efficient available, there’s still plenty of room for improvement. Researchers recently found that light emitting diodes’ efficiency can be impeded by trace amounts of iron, which is a byproduct of LED production.
That conclusion was the result of an international study involving KTH Royal Institute of Technology in Stockholm, and other universities, including University of California Santa Barbara, Rutgers University, the University of Vienna and the Center for Physical Sciences and Technology in Lithuania.
In LED lighting fixtures, each tiny “bulb”, or light emitting diode (LED), contributes light through recombination of electrons and electron holes – the two charge carriers in semiconductors.
When electrons and holes recombine, they basically annihilate each other. The electrons fall into the empty state associated with the hole and what is emitted is the energy difference between the initial and final state of the electron. In the case of a radiative recombination, the emission is in the form of photons – or light.
In an ultraviolet, blue or green LED, this activity takes place inside a nanostructure based on the semiconductor material, gallium nitride (GaN). A bias voltage is applied via electric leads to inject electrons and holes into the nanostructure. However, if the semiconductor material contains many defects and impurities, such as iron, the resulting recombination may be nonradiative, Marcinkevicius says. “That is, it will produce heat instead of light. The faster this nonradiative recombination, the lower the efficiency of the LED.”
The researchers found that unintentional introduction of iron impurities – even at very modest concentrations (1015 cm–3) – leads to a substantial nonradiative recombination, with recombination rates similar to that of the radiative process.
Where does the iron come from? Apparently it may be introduced unintentionally from stainless steel reactors that are used for making LED structures.
“Since even miniscule iron concentrations affect the recombination process, iron in LED structures may be a serious culprit in the quest for the ultimate LED efficiency,” he says.
The finding is actually a corroboration of ideas Marcinkevicius had already been working with, and a direct result of his recent sabbatical at UCSB. Assisting him was PhD student, Tomas Uzdavinys.
“Just before this paper, we published an experimental paper on ultrafast electron dynamics in iron-doped gallium nitride, in Journal of Applied Physics. Trying to explain our experimental results, we arrived independently at similar ideas as the UCSB group, which is working with theoretical modelling.”